In .net 4.5 there is a new feature called Multicore JIT
It allows for performance improvements to app startup times.
However you need to enable it in code.
So why is it not on by default?
I wrote the blog post you linked to and Vance addresses your question in the embedded video around 30:15.
Multicore JIT is on by default for Silverlight 5 and ASP.NET applications, but not for desktop applications. The main reason for this is that the CLR needs a place to save and load the files containing the JIT profile information.
Silverlight 5 and ASP.NET applications are hosted applications and the host provides a good place to store the profile information. We also know that all of these applications have a similar startup path and will be able to take advantage of MCJ. For desktop applications we don't have a good location to put the profile, and not all applications will benefit from MCJ on process startup. For desktop applications, we chose to provide a set of APIs that can be used to "opt-in" if it will benefit your application.
Thanks for reading the post, and if you have seen any results from using the feature I'd love to hear about it!