Basic use of immediates vs. square brackets in YASM/NASM x86 assembly

Suppose I have the following declared:

section .bss
buffer    resb     1

And these instructions follow in section .text:

mov    al, 5                    ; mov-immediate
mov    [buffer], al             ; store
mov    bl, [buffer]             ; load
mov    cl, buffer               ; mov-immediate?

Am I correct in understanding that bl will contain the value 5, and cl will contain the memory address of the variable buffer?

I am confused about the differences between

moving an immediate into a register,
moving a register into an immediate (what goes in, the data or the address?) and
moving an immediate into a register without the brackets
- For example, mov cl, buffer vs mov cl, [buffer]

UPDATE: After reading the responses, I suppose the following summary is accurate:

mov edi, array puts the memory address of the zeroth array index in edi. i.e. the label address.
mov byte [edi], 3 puts the VALUE 3 into the zeroth index of the array
after add edi, 3, edi now contains the memory address of the 3rd index of the array
mov al, [array] loads the DATA at the zeroth index into al.
mov al, [array+3] loads the DATA at the third index into al.
mov [al], [array] is invalid because x86 can't encode 2 explicit memory operands, and because al is only 8 bits and can't be used even in a 16-bit addressing mode. Referencing the contents of a memory location. (x86 addressing modes)
mov array, 3 is invalid, because you can't say "Hey, I don't like the offset at which array is stored, so I'll call it 3". An immediate can only be a source operand.
mov byte [array], 3 puts the value 3 into the zeroth index (first byte) of the array. The byte specifier is needed to avoid ambiguity between byte/word/dword for instructions with memory, immediate operands. That would be an assemble-time error (ambiguous operand size) otherwise.

Please mention if any of these is false. (editor's note: I fixed syntax errors / ambiguities so the valid ones actually are valid NASM syntax. And linked other Q&As for details)

Solution

Indeed, your thought is correct.That is, bl will contain 5 and cl the memory address of buffer(in fact the label buffer is a memory address itself).

Now, let me explain the differences between the operations you mentioned:

moving an immediate into a register can be done using mov reg,imm.What may be confusing is that labels e.g buffer are immediate values themselves that contain an address.
You cannot really move a register into an immediate, since immediate values are constants, like 2 or FF1Ah.What you can do is move a register to the place where the constant points to.You can do it like mov [const], reg .
You can also use indirect addressing like mov reg2,[reg1] provided reg1 points to a valid location, and it will transfer the value pointed by reg1 to reg2.

So, mov cl, buffer will move the address of buffer to cl(which may or may not give the correct address, since cl is only one byte long) , whereas mov cl, [buffer] will get the actual value.

Summary

When you use [a], then you refer to the value at the place where a points to.For example, if a is F5B1, then [a] refers to the address F5B1 in RAM.
Labels are addresses,i.e values like F5B1.
Values stored in registers do not have to be referenced to as [reg] because registers do not have addresses.In fact, registers can be thought of as immediate values.