First of all you have to enable this workflow from azure and if you do , you can then send a simple POST request like this:
curl --location --request POST 'https://{{TENAT_ID}}.b2clogin.com/{{TENAT_ID}}.onmicrosoft.com/{{AUTHORITY}}/oauth2/v2.0/token' \
--header 'response_type: token' \
--header 'Content-Type: application/x-www-form-urlencoded' \
--data-urlencode 'response_type=token id_token' \
--data-urlencode 'scope={{SCOPE}} {{CLIENT_ID}}' \
--data-urlencode 'client_id={{CLIENT_ID}}' \
--data-urlencode 'username={{USER_NAME}}' \
--data-urlencode 'password={{USER_PASSWORD}}' \
--data-urlencode 'grant_type=password'
you can easily import this to post man and change the {{ }} with your own settings