I am using LAPACK's ssteqr function to calculate eigenvalues/eigenvectors. The documentation for ssteqr says that the eigenvalues are sorted "in ascending order". Is it reasonable to assume that the list of eigenvectors is also sorted in ascending order?
Yes, it is reasonable to assume that the eigenvectors are ordered so that the i-th eigenvector corresponds to the i-th eigenvalue.
Nevertheless, if I were you, I would check for each eigenvalue the result of the multiplication of the eigenvector by the matrix. This way you are sure that you interpret the output right, and you see explicitly the accuracy of the calculations.