You can lookup built-in functions by searching for e.g. PHPAPI(stream_copy_to_stream) and find the implementation in ext/standard/streamsfuncs.c.
How to do that for a language construct like echo?
I found it is associated with T_ECHO in Zend/zend_language_parser.y but couldn't trace how it works from there.
Where does Zend Engine implement echo functionality?
Given this example program:
<?php echo 'Hello world!';
We can obtain the opcodes that the program is compiled to like so:
$ phpdbg7.4 -p /tmp/hello.php
function name: (null)
L1-2 {main}() /tmp/hello.php - 0x7fef35ea1000 + 3 ops
L1 #0 EXT_STMT
L1 #1 ECHO "Hello world!"
L2 #2 RETURN<-1> 1
As you can see, echo is handled using a separate VM instruction: ZEND_ECHO. The handlers for each opcode is defined in Zend/zend_vm_def.h. Search for "ZEND_ECHO".