I haven't been able to find what these Xcode icons mean. Some you can deduce (cup icon is cocoa, person icon is your code) but other's are more mysterious.
UPDATE 1:
I was able to find the icon files under:
.../Xcode.app/Contents/PlugIns/DebuggerFoundation.ideplugin/Contents/Resources
There's a total of 13 different icons and they are all clearly labeled. In the screenshot that I posted we have:
Update 2:
A while back I wrote a blog post that's easier to read: http://jlmendezbonini.com/2013/03/27/Xcode-4-debugger-icons.html
Update 3:
Looks like Apple finally documented it in the Process View Display section. Here's a link to the image:
The icon means, in general, assembly for which you don't have debugging symbols. Not your code (the person icon), not public, top-level Cocoa code (the mug), not Framework/library code (the suitcase) but plain old assembly.
I don't think this is documented anywhere (I haven't seen it) but it seems to hold true for all the tests I've done.