I know that some website are applications, but not all websites are applications (albeit maybe just a brochure viewing site)
Is there an in depth dummy use case for a brochure type site which would be beneficial to use.
When it comes to a corporate front facing website for example I suffer from feature blindness, although for an actual database driven application (for example a purchase order system) I feel within my element.
Is there any resources that can help me view "brochure" sites in the same light than I do with a pro bono database driven applications.
Use Cases can be used to model requirements of a system. System is a structure with input and output mappings. So if you have a static web page, you cannot interact with it in a other way than to view it.
As discussed in comments, if you think you did not understood the goals of stakeholders (what that word document sent by your boss ment...), you have to ask more and find them, use cases are a good technique for this.
In a cycle, discover actors (systems and roles interacting with the system you have to develop) and use cases (what needs of those actors the developed system should ssatisfy). Every time you find an actor, you may ask what other needs (possible use cases) he has and when you find an use case, you should ask who will participate in it and who is interested in it (who is the next actor and who are the stakeholders). Then you can define the scope boundaries and prioritize...