How to obtain the hex value 0xffff corresponding to the decimal value -0.000061 in the table below?
Right at the beginning of this page The OpenType Font File you'll find this table, with examples of the F2DOT14 format for a 16-bit signed fixed number with the low 14 bits of a fraction.
I couldn't obtain the hex value 0xffff for the decimal -0.000061. By the way the mantissa -1 seems to be wrong and the value for the fraction should be 1/16384, instead of 16383/16384, unless I'm missing something related to the two's complement notation used to express a negative value in code.
The mantissa and fraction values listed are entirely correct: the F2DOT14 field encodes numbers as the arithmetic computation mantissa + fraction, not as "signed mantissa with unsigned concatenated fraction remainder".
As such, if you want -0.000061, you have to start with the signed integer -1 in the first two bits (11) and then add the positive value 16383/16384 in the last 14 bits (11111111111111), such that mantissa + fraction = -1 + 16383/16384 = -1/16384, which in turn is encoded using the 16 bit code 0xFFFF