Is this possible or is it not valid?
<h1>
<button>
Caption
</button>
</h1>
This header is the heading of an accordion. Therefore its a button as it opens and closes the accordion but semantically its a header as its the important chapters of the page. What do you suggest?
First of all, try the W3C Validator instead of opening a new question every time you want to know if your HTML is valid.
Now to your question - yes it is valid.