Setting up SQLServer with XA Drivers contains a step where you must assign users to the role called "SqlJDBCXAUser"; this can be done using "sp_addrolemember" sproc and undone using the "sp_droprolemember".
Is there a way of checking whether a particular user has been assigned that role ?
Or (better): a way of just listing ALL users assigned to use the specific role here ?
You can use IS_MEMBER
See the manual here - http://msdn.microsoft.com/en-us/library/ms186271.aspx
To list members, use sp_helprolemember
or see How to list role members in SQL Server 2008 R2