This is vgs5.conf saved to C:/wamp/
Alias /vgs5/ "//Serv-lt/vgs5"
<Directory "//Serv-lt/vgs5">
Options Indexes FollowSymLinks MultiViews
AllowOverride all
Order allow,deny
Allow from all
</Directory>
When I go to [http://127.0.0.1/vgs5] using firefox it shows me the directory contents. When I go to [http://127.0.0.1/vgs5/xxx.pdf] using firefox it shows 404 Not Found. Although the file xxx.pdf does exist and is viewable at \\Serv-lt\vgs5\xxx.pdf in adobe.
WampServer Version 2.2
Apache 2.2.22
This is what worked
Alias /vgs5 "//Serv-lt/vgs5"
<Directory "//Serv-lt/vgs5">
Options Indexes FollowSymLinks MultiViews
AllowOverride all
Order allow,deny
Allow from all
</Directory>