Xcode version is 5.0.2 with latest iOS system.
I changed run's scheme build configuration to release, then click Run to build app, after that:
But when I changed run's scheme build configuration to debug, it works fine.
Note: Code Signing using iOS Developer both debug and release.
In XCode (not in Instruments) select Product > Profile, and after if compiles, choose automation. Wait for the app to start, then stop the track: you should be able to run it from the editor. If not, delete the Instruments and iPhone Simulator folders from the Library and restart Instruments.