From the W3C:
If an HTML document does not start with a BOM, and its encoding is not explicitly given by Content-Type metadata, and the document is not an iframe srcdoc document, then the character encoding used must be an ASCII-compatible character encoding
So How I can add a BOM which would mean the document is encoded in UTF16 for example?
The byte order mask is an hex sequence which can be put at the beginning of any file.
It has nothing to do with the html/other web languages.
An hex editor is a good way to add it.
Although UTF-32 offer the advantage of fixed length encoding, some browser/e-mail client dropped the support for it.
note: UTF-16 is mainly used on windows.