I have search around and can see many questions on converting values but I cant find a library that gives me the CMYK values, I can only see examples that get the RGB values?
If there a library that can open CMYK tif files and do this?
One option is to use LibTiff.Net library (disclaimer: I am one of it's developers). The library can provide access to data in TIFF without conversion of the data.
Following methods might be useful for you:
There are also Getting Started tutorial and some samples.