Can I use MongoDB and a PostgreSQL in one rails app? Specifically I will eventually want to use something like MongoHQ. So far I have failed to get this working in experimentation. And it concerns me that the MongoDB documentation specifically says I have to disable ActiveRecord. Any advice would be appreciated.
You don't need to disable ActiveRecord to use MongoDB. Check out Mongoid and just add the gem plus any models along side any of your existing ActiveRecord models. You should note that MongoHQ is just a hosting service for MongoDB and can be used alongside any Object Document Mapper (ODM).
For further details check http://mongoid.org/en/mongoid/docs/installation.html. Just skip the optional 'Getting Rid of Active Record' step.